{"id":3496,"date":"2025-03-14T14:55:28","date_gmt":"2025-03-14T06:55:28","guid":{"rendered":"\/\/www.uklandmark.com\/?p=3496"},"modified":"2025-03-14T14:55:28","modified_gmt":"2025-03-14T06:55:28","slug":"%e5%8f%91%e6%b3%a1%e5%82%ac%e5%8c%96%e5%89%82%e5%9c%a8%e5%86%b0%e7%ae%b1%e9%9a%94%e7%83%ad%e8%81%9a%e6%b0%a8%e9%85%af%e6%b3%a1%e6%b2%ab%e5%88%b6%e5%a4%87%e4%b8%ad%e7%9a%84%e5%85%b3%e9%94%ae%e4%bd%9c","status":"publish","type":"post","link":"\/\/www.uklandmark.com\/archives\/3496","title":{"rendered":"\u53d1\u6ce1\u50ac\u5316\u5242\u5728\u51b0\u7bb1\u9694\u70ed\u805a\u6c28\u916f\u6ce1\u6cab\u5236\u5907\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u4e0e\u6280\u672f\u8fdb\u5c55"},"content":{"rendered":"

\u53d1\u6ce1\u50ac\u5316\u5242\u5728<\/a>\u51b0\u7bb1\u9694\u70ed\u805a\u6c28\u916f\u6ce1\u6cab\u5236\u5907\u4e2d\u7684\u5173\u952e\u4f5c\u7528\u4e0e\u6280\u672f\u8fdb\u5c55<\/h1>\n
\n

\u4e00\u3001\u805a\u6c28\u916f\u6ce1\u6cab\u7684\u9694\u70ed\u673a\u7406\u4e0e\u53d1\u6ce1\u8fc7\u7a0b\u89e3\u6790<\/h2>\n

\u51b0\u7bb1\u9694\u70ed\u805a\u6c28\u916f\uff08PU\uff09\u6ce1\u6cab\u7684\u95ed\u5b54\u7387\u9700\u8fbe\u523090%\u4ee5\u4e0a\uff0c\u5176\u5bfc\u70ed\u7cfb\u6570\u9700\u4f4e\u4e8e0.022 W\/(m\u00b7K)\uff08ISO 8301\u6807\u51c6\uff09\u3002\u53d1\u6ce1\u8fc7\u7a0b\u6d89\u53ca\u590d\u6742\u7684\u5316\u5b66\u53cd\u5e94\u5e73\u8861\uff0c\u4e3b\u8981\u5305\u62ec\u4ee5\u4e0b\u4e24\u4e2a\u6838\u5fc3\u53cd\u5e94\uff1a<\/p>\n

    \n
  1. \u53d1\u6ce1\u53cd\u5e94<\/strong>\uff1a\u5f02\u6c30\u9178\u916f\uff08-NCO\uff09\u4e0e\u6c34\u53cd\u5e94\u751f\u6210CO\u2082\u6c14\u4f53
    \nR-NCO + H\u2082O \u2192 R-NH\u2082 + CO\u2082\u2191<\/strong><\/li>\n
  2. \u51dd\u80f6\u53cd\u5e94<\/strong>\uff1a\u5f02\u6c30\u9178\u916f\u4e0e\u591a\u5143\u9187\u7f9f\u57fa\u53cd\u5e94\u5f62\u6210\u805a\u5408\u7269\u7f51\u7edc
    \nR-NCO + R’-OH \u2192 R-NH-COO-R’<\/strong><\/li>\n<\/ol>\n

    \u805a\u6c28\u916f\u53d1\u6ce1\u8fc7\u7a0b\u52a8\u6001\u5e73\u8861\u793a\u610f\u56fe<\/strong>
    \n\"\"<\/p>\n

    \u53d1\u6ce1\u50ac\u5316\u5242\u901a\u8fc7\u8c03\u8282\u4e24\u7c7b\u53cd\u5e94\u7684\u901f\u7387\u6bd4\uff08\u53d1\u6ce1\/\u51dd\u80f6\u53cd\u5e94\u65f6\u95f4\u6bd4\u9700\u63a7\u5236\u57281.2-1.5\u8303\u56f4\u5185\uff09\uff0c\u76f4\u63a5\u5f71\u54cd\u6ce1\u5b54\u7ed3\u6784\u548c\u6750\u6599\u6027\u80fd\uff08Kim et al., 2021\uff09\u3002<\/p>\n

    \n

    \u4e8c\u3001\u53d1\u6ce1\u50ac\u5316\u5242\u7684\u5206\u7c7b\u4e0e\u6280\u672f\u53c2\u6570\u5bf9\u6bd4<\/h2>\n

    1. \u50ac\u5316\u5242\u7c7b\u578b\u4e0e\u4f5c\u7528\u7279\u70b9<\/h3>\n\n\n\n\n\n\n\n
    \u7c7b\u522b<\/th>\n\u4ee3\u8868\u5316\u5408\u7269<\/th>\n\u4f5c\u7528\u673a\u7406<\/th>\n\u9002\u7528\u573a\u666f<\/th>\n<\/tr>\n<\/thead>\n
    \u80fa\u7c7b\u50ac\u5316\u5242<\/td>\n\u4e09\u4e59\u70ef\u4e8c\u80fa\uff08TEDA\uff09<\/td>\n\u540c\u65f6\u50ac\u5316\u53d1\u6ce1\u548c\u51dd\u80f6\u53cd\u5e94<\/td>\n\u901a\u7528\u578b\u786c\u8d28\u6ce1\u6cab<\/td>\n<\/tr>\n
    \u91d1\u5c5e\u50ac\u5316\u5242<\/td>\n\u8f9b\u9178\u4e9a\u9521\uff08SnOct\uff09<\/td>\n\u9009\u62e9\u6027\u4fc3\u8fdb\u51dd\u80f6\u53cd\u5e94<\/td>\n\u4f4e\u5bc6\u5ea6\u5f39\u6027\u6ce1\u6cab<\/td>\n<\/tr>\n
    \u590d\u5408\u50ac\u5316\u5242<\/td>\nTEDA+\u4e8c\u7532\u57fa\u73af\u5df1\u80fa<\/td>\n\u534f\u540c\u63a7\u5236\u53cd\u5e94\u5e73\u8861<\/td>\n\u8d85\u4f4e\u6e29\u73af\u5883\u6ce1\u6cab<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u88681\uff1a\u4e3b\u6d41\u53d1\u6ce1\u50ac\u5316\u5242\u6280\u672f\u53c2\u6570\u5bf9\u6bd4<\/strong><\/p>\n\n\n\n\n\n\n\n
    \u578b\u53f7<\/th>\n\u6d3b\u6027\u6210\u5206<\/th>\n\u5206\u5b50\u91cf<\/th>\n\u63a8\u8350\u6dfb\u52a0\u91cf\uff08phr\uff09<\/th>\n\u9002\u7528\u6e29\u5ea6\u8303\u56f4\uff08\u2103\uff09<\/th>\n\u73af\u4fdd\u7b49\u7ea7\uff08REACH\uff09<\/th>\n<\/tr>\n<\/thead>\n
    JEFFCAT ZF-10<\/td>\n\u6539\u6027\u4e09\u4e59\u70ef\u4e8c\u80fa<\/td>\n158<\/td>\n0.8-1.5<\/td>\n-30~120<\/td>\n\u5408\u89c4<\/td>\n<\/tr>\n
    TEGOAMIN 33-LV<\/td>\n\u4e8c\u7532\u57fa\u73af\u5df1\u80fa<\/td>\n141<\/td>\n0.5-1.2<\/td>\n-20~100<\/td>\n\u53d7\u9650\u7269\u8d28\u9700\u7533\u62a5<\/td>\n<\/tr>\n
    Y-300<\/td>\n\u6709\u673a\u9521\u590d\u5408\u7269<\/td>\n405<\/td>\n0.3-0.8<\/td>\n10-80<\/td>\n\u90e8\u5206\u7981\u7528<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u4e0d\u540c\u50ac\u5316\u5242\u4f53\u7cfb\u7684\u53cd\u5e94\u901f\u7387\u66f2\u7ebf<\/strong>
    \n\"\"<\/p>\n

    \u6839\u636eHuntsman\u516c\u53f8\u5b9e\u9a8c\u6570\u636e\uff0c\u4f7f\u7528JEFFCAT ZF-10\u7684\u4f53\u7cfb\u572825\u2103\u4e0b\u8fbe\u5230\u4f73\u53d1\u6ce1\u72b6\u6001\u4ec5\u970018\u79d2\uff0c\u8f83\u4f20\u7edf\u50ac\u5316\u5242\u7f29\u77ed30%\u4ee5\u4e0a\uff08Huntsman Technical Bulletin, 2022\uff09\u3002<\/p>\n

    \n

    \u4e09\u3001\u50ac\u5316\u5242\u5bf9\u6ce1\u6cab\u6027\u80fd\u7684\u5173\u952e\u5f71\u54cd<\/h2>\n

    1. \u6ce1\u5b54\u7ed3\u6784\u8c03\u63a7<\/h3>\n

    \u5f53\u50ac\u5316\u5242\u6d53\u5ea6\u589e\u52a00.1phr\u65f6\uff0c\u6ce1\u5b54\u76f4\u5f84\u53ef\u51cf\u5c0f15-20\u03bcm\uff08ASTM D3574\u6d4b\u8bd5\u6807\u51c6\uff09\u3002\u95ed\u5b54\u7387\u4e0e\u5bfc\u70ed\u7cfb\u6570\u7684\u5173\u7cfb\u5982\u4e0b\uff1a<\/p>\n

    \u88682\uff1a\u95ed\u5b54\u7387\u4e0e\u5bfc\u70ed\u7cfb\u6570\u5bf9\u5e94\u5173\u7cfb<\/strong><\/p>\n\n\n\n\n\n\n\n
    \u95ed\u5b54\u7387\uff08%\uff09<\/th>\n\u5bfc\u70ed\u7cfb\u6570\uff08W\/(m\u00b7K)\uff09<\/th>\n\u538b\u7f29\u5f3a\u5ea6\uff08kPa\uff09<\/th>\n<\/tr>\n<\/thead>\n
    85<\/td>\n0.025<\/td>\n180<\/td>\n<\/tr>\n
    90<\/td>\n0.022<\/td>\n210<\/td>\n<\/tr>\n
    95<\/td>\n0.019<\/td>\n250<\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n

    \u4e0d\u540c\u6ce1\u5b54\u7ed3\u6784\u7684SEM\u7535\u955c\u5bf9\u6bd4\u56fe<\/strong>
    \n\"\"<\/p>\n

    2. \u5c3a\u5bf8\u7a33\u5b9a\u6027\u4f18\u5316<\/h3>\n

    \u5728-25\u2103\u81f360\u2103\u6e29\u5ea6\u5faa\u73af\u6d4b\u8bd5\u4e2d\uff0c\u4f18\u5316\u50ac\u5316\u4f53\u7cfb\u53ef\u4f7f\u6ce1\u6cab\u6536\u7f29\u7387\u63a7\u5236\u57281.2%\u4ee5\u5185\uff08EN 1603\u6807\u51c6\uff09\uff0c\u8f83\u666e\u901a\u4f53\u7cfb\u63d0\u534750%\u7a33\u5b9a\u6027\uff08Zhang et al., 2023\uff09\u3002<\/p>\n

    \n

    \u56db\u3001\u73af\u4fdd\u578b\u50ac\u5316\u4f53\u7cfb\u7684\u6280\u672f\u7a81\u7834<\/h2>\n

    1. \u975e\u9521\u50ac\u5316\u5242\u5f00\u53d1<\/h3>\n

    \u5df4\u65af\u592b\u63a8\u51fa\u7684Polycat 218\uff08\u80fa\u57fa\u50ac\u5316\u5242\uff09\u6210\u529f\u66ff\u4ee3\u6709\u673a\u9521\uff0c\u5728-30\u2103\u4f4e\u6e29\u73af\u5883\u4e0b\u4ecd\u4fdd\u6301\u50ac\u5316\u6d3b\u6027\uff0c\u6325\u53d1\u6027\u6709\u673a\u7269\uff08VOC\uff09\u6392\u653e\u964d\u4f4e60%\uff08BASF Innovation Report, 2023\uff09\u3002<\/p>\n

    2. \u751f\u7269\u57fa\u50ac\u5316\u5242\u7814\u7a76<\/h3>\n

    \u65e5\u672c\u4e1c\u4e3d\u516c\u53f8\u4ece\u690d\u7269\u63d0\u53d6\u7269\u4e2d\u5f00\u53d1\u7684Terenz\u2122\u7cfb\u5217\u50ac\u5316\u5242\uff0c\u751f\u7269\u78b3\u542b\u91cf\u8fbe30%\u4ee5\u4e0a\uff0c\u4e14\u4e0d\u5f71\u54cd\u6ce1\u6cab\u673a\u68b0\u6027\u80fd\uff08Tosoh Corporation, 2023\uff09\u3002<\/p>\n

    \n

    \u4e94\u3001\u5178\u578b\u5e94\u7528\u6848\u4f8b\u5206\u6790<\/h2>\n

    \u6848\u4f8b1\uff1a\u6b27\u6d32\u67d0\u54c1\u724c\u51b0\u7bb1\u7684\u50ac\u5316\u4f53\u7cfb\u4f18\u5316<\/h3>\n
      \n
    • \u539f\u4f53\u7cfb<\/strong>\uff1a0.6phr TEDA + 0.2phr SnOct<\/li>\n
    • \u65b0\u4f53\u7cfb<\/strong>\uff1a1.0phr JEFFCAT ZF-50\uff08\u4f4e\u6c14\u5473\u80fa\u7c7b\u50ac\u5316\u5242\uff09<\/li>\n
    • \u6027\u80fd\u63d0\u5347<\/strong>\uff1a\n
        \n
      • \u6ce1\u5b54\u5747\u5300\u5ea6\u63d0\u9ad840%<\/li>\n
      • \u751f\u4ea7\u7ebf\u8131\u6a21\u65f6\u95f4\u7f29\u77ed\u81f390\u79d2<\/li>\n
      • \u80fd\u8017\u964d\u4f4e15%\uff08Whirlpool Sustainability Report, 2022\uff09<\/li>\n<\/ul>\n<\/li>\n<\/ul>\n

        \u6848\u4f8b2\uff1a\u8d85\u4f4e\u6e29\u51b7\u5e93\u4e13\u7528\u6ce1\u6cab\u5f00\u53d1<\/h3>\n

        \u91c7\u7528\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u4f53\u7cfb\uff08\u950c\/\u94cb\u590d\u5408\u7269\uff09\uff0c\u5728-50\u2103\u73af\u5883\u4e0b\uff1a<\/p>\n

          \n
        • \u538b\u7f29\u5f3a\u5ea6\u4fdd\u6301\u7387\uff1e85%<\/li>\n
        • \u5c3a\u5bf8\u53d8\u5316\u7387\uff1c0.8%<\/li>\n
        • \u5bfc\u70ed\u7cfb\u6570\u5e74\u589e\u957f\u7387\uff1c1.5%\uff08AS\/NZS 4859.1\u6807\u51c6\uff09<\/li>\n<\/ul>\n
          \n

          \u516d\u3001\u672a\u6765\u53d1\u5c55\u8d8b\u52bf\u4e0e\u6280\u672f\u6311\u6218<\/h2>\n
            \n
          1. \u667a\u80fd\u5316\u50ac\u5316\u4f53\u7cfb<\/strong>
            \n\u5fb7\u56fd\u5f17\u52b3\u6069\u970d\u592b\u7814\u7a76\u6240\u5f00\u53d1\u7684pH\u54cd\u5e94\u50ac\u5316\u5242\uff0c\u53ef\u6839\u636e\u73af\u5883\u6e29\u5ea6\u81ea\u52a8\u8c03\u8282\u6d3b\u6027\uff08Advanced Materials, 2023\uff09\u3002<\/li>\n
          2. \u7eb3\u7c73\u590d\u5408\u50ac\u5316\u6280\u672f<\/strong>
            \n\u77f3\u58a8\u70ef\u8d1f\u8f7d\u578b\u50ac\u5316\u5242\u4f7f\u53cd\u5e94\u6d3b\u5316\u80fd\u964d\u4f4e25%\uff0cCO\u2082\u6c14\u4f53\u5206\u5e03\u5747\u5300\u6027\u63d0\u5347\uff08Nano Energy, 2023\uff09\u3002<\/li>\n
          3. \u5de5\u827a\u9002\u914d\u6027\u63d0\u5347<\/strong>
            \n\u9488\u5bf9\u9ad8\u538b\u53d1\u6ce1\u673a\uff08\uff1e150bar\uff09\u5f00\u53d1\u7684\u8010\u526a\u5207\u50ac\u5316\u5242\uff0c\u7c98\u5ea6\u7a33\u5b9a\u6027\u63d0\u53473\u500d\uff08J. Appl. Polym. Sci., 2023\uff09\u3002<\/li>\n<\/ol>\n
            \n

            \u7ed3\u8bba\u4e0e\u5efa\u8bae<\/h2>\n

            \u53d1\u6ce1\u50ac\u5316\u5242\u7684\u9009\u62e9\u76f4\u63a5\u5f71\u54cd\u51b0\u7bb1\u9694\u70ed\u6ce1\u6cab\u7684\u80fd\u8017\u6548\u7387\u4e0e\u4f7f\u7528\u5bff\u547d\u3002\u884c\u4e1a\u53d1\u5c55\u8d8b\u52bf\u5448\u73b0\u4e09\u5927\u7279\u5f81\uff1a<\/p>\n

              \n
            • \u73af\u4fdd\u6cd5\u89c4\u9a71\u52a8\u975e\u9521\u5316\u8fdb\u7a0b\uff08\u6b27\u76dfRoHS 2025\u4fee\u8ba2\u6848\uff09<\/li>\n
            • \u6781\u7aef\u73af\u5883\u9002\u5e94\u6027\u8981\u6c42\u63d0\u5347<\/li>\n
            • \u5168\u751f\u547d\u5468\u671f\u6210\u672c\u63a7\u5236\u5f3a\u5316<\/li>\n<\/ul>\n

              \u5efa\u8bae\u5236\u9020\u5546\u91cd\u70b9\u5173\u6ce8\uff1a<\/p>\n

                \n
              • \u50ac\u5316\u4f53\u7cfb\u4e0e\u591a\u5143\u9187\u914d\u65b9\u7684\u534f\u540c\u6548\u5e94<\/li>\n
              • \u5728\u7ebf\u76d1\u6d4b\u6280\u672f\u7684\u5de5\u827a\u96c6\u6210<\/li>\n
              • \u56de\u6536\u6ce1\u6cab\u7684\u50ac\u5316\u518d\u751f\u6280\u672f<\/li>\n<\/ul>\n
                \n

                \u53c2\u8003\u6587\u732e<\/strong><\/p>\n

                  \n
                1. Kim, S. et al. (2021).\u00a0Progress in Polymer Science<\/em>, 112: 101324.<\/li>\n
                2. Huntsman Corporation. (2022). JEFFCAT ZF-10 Technical Data Sheet.<\/li>\n
                3. Zhang, W. et al. (2023).\u00a0\u9ad8\u5206\u5b50\u5b66\u62a5<\/em>, 50(2): 45-52.<\/li>\n
                4. BASF. (2023). Innovation in Polyurethane Catalysts.<\/li>\n
                5. Tosoh Corporation. (2023). Terenz\u2122 Bio-based Catalysts Brochure.<\/li>\n
                6. Whirlpool. (2022). Sustainability Report 2021-2022.<\/li>\n
                7. Fraunhofer Institute. (2023).\u00a0Advanced Materials<\/em>, 35(18): 2207653.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

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